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Abstract #4495

Chemical Exchange Saturation Transfer & R1rho Dispersions of Polypeptides with Varying Complexities

Ke Li1,2, Jared G. Cobb1,3, Jingping Xie1,2, Zhongliang Zu1,2, Daniel F. Gochberg1,2, John C. Gore1,2

1Institute of Imaging Science, Vanderbilt University, Nashville, TN, United States; 2Department of Radiology, Vanderbilt University, Nashville, TN, United States; 3Department of Biomedical Engineering, Vanderbilt University, Nashville, TN, United States


Chemical exchange saturation transfer (CEST) imaging techniques have been developed to detect the proton exchange between water and mobile solute molecules which contain exchangeable protons. We hypothesize that CEST contrast and T1ρ relaxation rates are sensitive to the complexity of exchanging molecule and not just the amide content. To test this idea, preliminary studies were performed on a poly-L-Lysine (PLL) model system with different molecular weights, thus different complexities.